Aluminium

metallic chemical element of silvery appearance with symbol Al and atomic number 13
(Redirected from Aluminum)

Aluminium (in American and Canadian English also: aluminum) is a chemical element. The symbol for aluminium is Al, and its atomic number is 13. Aluminium is the most abundant metal.

Aluminium,  13Al
Aluminium-4.jpg
General properties
Pronunciation
Alternative namealuminum (U.S., Canada)
Appearancesilvery gray metallic
Standard atomic weight (Ar, standard)26.9815384(3)[1]
Aluminium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
B

Al

Ga
magnesiumaluminiumsilicon
Atomic number (Z)13
Groupgroup 13 (boron group)
Periodperiod 3
Blockp-block
Element category  post-transition metal, sometimes considered a metalloid
Electron configuration[Ne] 3s2 3p1
Electrons per shell
2, 8, 3
Physical properties
Phase at STPsolid
Melting point933.47 K ​(660.32 °C, ​1220.58 °F)
Boiling point2743 K ​(2470 °C, ​4478 °F)
Density (near r.t.)2.70 g/cm3
when liquid (at m.p.)2.375 g/cm3
Heat of fusion10.71 kJ/mol
Heat of vaporization284 kJ/mol
Molar heat capacity24.20 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 1482 1632 1817 2054 2364 2790
Atomic properties
Oxidation states−2, −1, +1,[2] +2,[3] +3 (an amphoteric oxide)
ElectronegativityPauling scale: 1.61
Ionization energies
  • 1st: 577.5 kJ/mol
  • 2nd: 1816.7 kJ/mol
  • 3rd: 2744.8 kJ/mol
  • (more)
Atomic radiusempirical: 143 pm
Covalent radius121±4 pm
Van der Waals radius184 pm
Color lines in a spectral range
Spectral lines of aluminium
Other properties
Natural occurrenceprimordial
Crystal structureface-centered cubic (fcc)
Face-centered cubic crystal structure for aluminium
Speed of sound thin rod(rolled) 5000 m/s (at r.t.)
Thermal expansion23.1 µm/(m·K) (at 25 °C)
Thermal conductivity237 W/(m·K)
Electrical resistivity26.5 nΩ·m (at 20 °C)
Magnetic orderingparamagnetic[4]
Magnetic susceptibility+16.5·10−6 cm3/mol
Young's modulus70 GPa
Shear modulus26 GPa
Bulk modulus76 GPa
Poisson ratio0.35
Mohs hardness2.75
Vickers hardness160–350 MPa
Brinell hardness160–550 MPa
CAS Number7429-90-5
History
Namingafter alumina (aluminium oxide), itself named after mineral alum
PredictionAntoine Lavoisier (1782)
Discovery and first isolationHans Christian Ørsted (1824)
Named byHumphry Davy (1812)
Main isotopes of aluminium
Iso­tope Abun­dance Half-life (t1/2) Decay mode Pro­duct
26Al trace 7.17×105 y β+ 26Mg
ε 26Mg
γ
27Al 100% stable
| references

HistoryEdit

People have tried to produce aluminium since 1760. The first successful attempt, finished in 1824 by Danish physicist and chemist Hans Christian Ørsted. He reacted anhydrous aluminium chloride with potassium amalgam, yielding a lump of metal looking similar to tin. He presented his results and showed a sample of the new metal in 1825.[7] In 1827, German chemist Friedrich Wöhler repeated Ørsted's experiments but did not identify any aluminium.[8] (The reason for this inconsistency was only discovered in 1921.) He conducted a similar experiment in the same year by mixing anhydrous aluminium chloride with potassium and produced a powder of aluminium.[9] In 1845, he was able to produce small pieces of the metal and described some physical properties of this metal. For many years thereafter, Wöhler was credited as personewho discovered of aluminium.

PropertiesEdit

Aluminium is a very good conductor of electricity and heat. It is light and strong. It can be hammered into sheets (malleable) or pulled out into wires (ductile). It is a highly reactive metal, although it is corrosion resistant.

A fresh film of aluminium is a good reflector of visible light and an excellent reflector of medium and far infrared radiation.

Aluminium prevents corrosion by forming a small, thin layer of aluminium oxide on its surface. This layer protects the metal by preventing oxygen from reaching it. Corrosion can not occur without oxygen. Because of this thin layer, the reactivity of aluminium is not seen. As a powder it burns hot. Uses include fireworks displays and rocket fuel.

Occurrence and preparationEdit

Pure aluminium is made from bauxite, a kind of rock that has aluminium oxide and many impurities. The bauxite is crushed and reacted with sodium hydroxide. The aluminium oxide dissolves. Then the aluminium oxide is dissolved in liquid cryolite, a rare mineral. Cryolite is normally produced artificially though. The aluminium oxide is electrolyzed to make aluminium and oxygen. The largest producer of aluminium is China. China produces about 31,873 thousand tonnes of aluminium.

Aluminium was once considered a precious metal that was even more valuable than gold. This is no longer true because, as technology improved, it became cheaper and easier to make pure metal.

In spaceEdit

It is the 12th most abundant of all elements. It is the 3rd most abundant among the elements that have odd atomic numbers.[10] The only stable isotope of aluminium is aluminium-27. It is the 18th most abundant nucleus in the Universe. It is created after fusion of carbon in massive stars that will later become Type II supernovae: this fusion creates magnesium-26, which, when capturing free protons and neutrons becomes aluminium. Essentially all aluminium now in existence is aluminium-27; aluminium-26 was there in the early Solar System but is now extinct. The trace quantities of aluminium-26 that do exist are the most common gamma ray emitter in the interstellar gas.[11]

On EarthEdit

Overall, the Earth is about 1.59% aluminium by mass.[12] In the Earth's crust, aluminium is the most abundant metallic element by mass (8.23%). It is also the third most abundant of all elements in the Earth's crust. A lot of silicates in the Earth's crust contain aluminium.[13] But, the Earth's mantle is only 2.38% aluminium by mass. Aluminium also occurs in seawater at a concentration of 2 μg/kg.[14]

Feldspars, the most common group of minerals in the Earth's crust, are aluminosilicates. Aluminium also occurs in the minerals beryl, cryolite, garnet, spinel, and turquoise.[15] Native aluminium has been reported in cold seeps in the northeastern continental slope of the South China Sea.

CompoundsEdit

Aluminium forms chemical compounds in the +3 oxidation state. They are generally unreactive. Aluminium chloride and aluminium oxide examples. Very rarely are compounds in the +1 or +2 oxidation state.

UsesEdit

Many things are made of aluminium. Much of it is used in overhead power lines. It is also widely used in window frames and aircraft bodies. It is found at home as kitchenware, soft drink cans, and cooking foil. Aluminium is also used to coat car headlamps and compact discs. It is used in electrical transmission lines because of its light weight. It can be deposited on the surface of glass to make mirrors, where a thin layer of aluminum oxide quickly forms that acts as a protective coating. Aluminum oxide is also used to make synthetic rubies and sapphires for lasers. Aluminum can now be produced from clay, but the process is not economically feasible at today.

Pure aluminium is very soft, so a harder metal is almost always added. The harder metal is usually copper. Copper/aluminium alloys are to make ships, because the aluminium prevents corrosion, and the copper prevents barnacles.

Aluminium compounds are used in deodorants, water processing plants, food additives, and antacids. Lithium aluminium hydride is a really strong reducing agent used in organic chemistry.

Aluminium sulfate is used in water treatment. It is also used as a mordant in dyeing, in pickling seeds, deodorizing of mineral oils, in leather tanning, and in production of other aluminium compounds.

Anhydrous aluminium chloride is used as a catalyst in chemical and petrochemical industries, the dyeing industry, and in synthesis of many inorganic and organic compounds.

Aluminium hydroxychlorides are used in purifying water, in the paper industry, and as antiperspirants. Sodium aluminate is used in treating water and as an accelerator for drying of cement.

Aluminium acetate in solution is used as an astringent.

Aluminium phosphate is used to make glass, ceramic, pulp and paper products, cosmetics, paints, varnishes. Aluminium hydroxide is used as an antacid, and mordant. It is used also in water purification, the manufacture of glass and ceramics, and in the waterproofing of fabrics.

Aluminium is used in automobiles, trucks, railway cars, marine vessels, bicycles, spacecraft. Aluminium is used in making doors, siding, building wire, sheathing, roofing and other building materials.

RecyclingEdit

Since aluminium needs to be made by electrolysis, it requires a very large amount of electrical power. Recycling aluminium would be much cheaper. That's why recycling plants were opened. The cost of recycling aluminium is much less than the cost of making it from bauxite.

Recycling involves melting the scrap. This is a process that only needs 5% of the energy used to produce aluminium from ore. But, 15% of the input material part is lost as dross (ash-like oxide).[16] An aluminium stack melter makes a lot less dross, about 1%.[17]

White dross from primary aluminium production and from secondary recycling processes still contains useful amounts of aluminium that can be extracted industrially. The process produces aluminium billets, together with a very complex waste. This waste is difficult to manage. It reacts with water, releasing a mixture of gases (including, hydrogen, acetylene, and ammonia), which ignites on contact with air.[18] Even with these difficulties, the waste is used as a filler in asphalt and concrete.[19]

ToxicityEdit

Aluminium is not used in the human body, although it is very common. People debate whether its use in deodorants and water treatment is healthy. Aluminium ions slow down plant growth in acidic soils. Aluminium may be a factor in Alzheimer's disease (a disease when the brain stops working and the patient is confused).[20][21] But the Alzheimer's Society says overwhelming medical and scientific opinion is that studies have not convincingly demonstrated a causal relationship between aluminium and Alzheimer's disease.[22]

In most people, aluminium is not as toxic as heavy metals. Aluminium is classified as a non-carcinogen by United States Department of Health and Human Services. There is little proof that normal exposure to aluminium is a risk to healthy adult. There is proof of no toxicity if it is taken in amounts not greater than 40 mg/day per kg of body mass.[23] Most aluminium taken will leave the body in feces. Most of the small part that enters the blood, will be excreted via urine.[24]

Aluminium rarely causes vitamin D-resistant osteomalacia, erythropoietin-resistant microcytic anemia, and central nervous system changes. People with kidney insufficiency are at a risk the most. Chronic ingestion of hydrated aluminium silicates may result in aluminium binding to the things in the intestines. It also increases the removal of other metals, like iron or zinc. Really high doses (>50 g/day) can cause anemia.

A small percentage of people have contact allergies to aluminium and experience itchy red rashes, headache, muscle pain, joint pain, poor memory, insomnia, depression, asthma, irritable bowel syndrome, or other symptoms when touching products containing aluminium.[25]

Exposure to powdered aluminium or aluminium welding fumes can cause pulmonary fibrosis. Fine aluminium powder can also explode.

Ways of exposureEdit

Food is the main source of aluminium. Drinking water has more aluminium than solid foods.[26] Aluminium in food may be absorbed more than aluminium from water. Major sources of human exposure by mouth to aluminium include food (because of its use in food additives, food and beverage packaging, and cooking utensils), drinking water (because of its use in water treatment), and medicines that have aluminium in it.[27] Very high exposure of aluminium are mostly limited to miners, aluminium production workers, and dialysis patients.[28]

Taking of antacids, antiperspirants, vaccines, and cosmetics give possible ways of exposure.[29] Eating acidic foods or liquids with aluminium increases aluminium absorption. Maltol has been shown to increase the build up of aluminium in nerve and bone tissues.[30]

TreatmentEdit

In case of suspected sudden consumption of a large amount of aluminium, the only treatment is deferoxamine mesylate. It may be given to help remove aluminium from the body by chelation.[31][32] But, this should be applied with caution as it not only reduce aluminium in the body, but can also reduce those of other metals such as copper or iron.[31]

Environmental effectsEdit

High levels of aluminium occur near mining sites. Small amounts of aluminium are released to the environment at the coal-fired power plants or incinerators. Aluminium in the air is washed out by the rain or normally settles down. But, small particles of aluminium remain in the air for a long time.[24]

Acid rain is the main natural factor to move aluminium from natural sources. It is also the main reason for the effects of aluminium on the environment.[33] The main factor for the presence of aluminium in salt and freshwater are the industrial processes that also release aluminium into air.[34]

In water, aluminium acts as a toxiс agent on animals that with gills like fish by causing loss of plasma- and hemolymph ions leading to osmoregulatory failure.[33]

Aluminium is one of the primary factors that reduce the growth of plants on acidic soils. In acid soils the concentration of toxic Al3+ cations increases and disturbs the growth and function of the root. It is generally harmless to plant growth in pH-neutral soils.[35][36][37][38] Wheat has developed a tolerance to aluminium. It releases organic compounds that bind to harmful aluminium cations. Sorghum is thought to have the same method of tolerating aluminium.[39]

Aluminium production has its own problems to the environment on each step of the production process. The major problem is the greenhouse gas. These gases are caused by the electrical consumption of the smelters and the byproducts of processing. The strongest of these gases are perfluorocarbons from the smelting process.[28]

A Spanish scientific report from 2001 claimed that the fungus Geotrichum candidum eats the aluminium in compact discs.[40][41] The better studied bacterium Pseudomonas aeruginosa and the fungus Cladosporium resinae are commonly found in aircraft fuel tanks that use kerosene-based fuels, and laboratory cultures can decompose aluminium.[42] However, these types of bacteria do not eat the aluminium; but rather, the metal is corroded by microbe waste products.[43]

GalleryEdit

 
Pure (white) and impure (yellow) forms of aluminium chloride
 
A roll of aluminium
 
Bauxite, aluminium ore
 
Aluminium cans ready for recycling at Central European Waste Management's plant in Europe

Related pagesEdit

ReferencesEdit

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