Arsine

chemical compound

Arsine, also known as arsenic hydride or hydrogen arsenide, is a chemical compound. Its chemical formula is AsH3. It has hydrogen and arsenide ions in it. The hydrogen is in its +1 oxidation state.

Properties

change

Arsine is a colorless gas. It is a reducing agent. It has a weak garlic odor. It easily burns to make arsenic trioxide in excess air or arsenic in small amounts of air. It breaks down to arsenic and hydrogen when heated. It can dissolve in water. It is heavier than air. Arsine reacts violently with oxidizing agents, such as the halogens.

Preparation

change

Arsine is made by reacting any arsenic(III) compound with any hydride. It can also be made by reacting any arsenide with an acid. It was first made by reacting zinc, hydrochloric acid, and arsenic trioxide.

Arsine is used to make semiconductors like gallium arsenide. It was looked at as a chemical weapon. It is almost odorless (it kills before one smells it), heavy (spreads along the ground), and colorless. It was unstable though, easily igniting.

Safety

change

Arsine is extremely toxic. 0.00005% (0.5 ppm) can poison people; 0.025% (250 ppm) quickly kills people.

change