|Low energy phenomena||Photoelectric effect|
|Mid-energy phenomena||Compton scattering|
|High energy phenomena||Pair production|
The photoelectric effect is a phenomenon in physics. The effect is based on the idea that electromagnetic radiation is made of a series of particles called photons. When a photon hits an electron on a metal surface, the electron can be emitted. The emitted electrons are called photoelectrons. The effect is also called the Hertz Effect, because it was discovered by Heinrich Rudolf Hertz, but this name is not used often. The photoelectric effect has helped physicists understand the quantum nature of light and electrons. The concept of wave–particle duality was developed because of the photoelectric effect. Albert Einstein proposed the Laws of Photoelectric Effect and won the Nobel Prize For Physics in 1921.
Not every electromagnetic wave will cause the photoelectric effect, only radiation of a certain frequency or higher will cause the effect. The minimum frequency needed is called the "cutoff frequency" or "threshold frequency'. The cutoff frequency is used to find the work function, w, which is the amount of energy holding the electron to the metal surface. The work function is a property of the metal and is not affected by the incoming radiation. If a frequency of light strikes the metal surface that is greater than the cutoff frequency, then the emitted electron will have some kinetic energy.
The energy of a photon causing the photoelectric effect is found through E = hf = KE + w, where h is Planck's constant, 6.626X10^(-34) J*s, f is the frequency of the electromagnetic wave, KE is the kinetic energy of the photoelectron and w is the work function for the metal. If the photon has a lot of energy, compton scattering(~thousands of eV) or pair production(~millions of eV) may take place.
The intensity of the light does not cause ejection of electrons, only light of the cut off frequency or higher can do that. However increasing the intensity of light will increase the number of electrons being emitted, as long as the frequency is above the cut off frequency.
The first observation of the photoelectric effect was by Heinrich Hertz in 1887. He reported that a spark jumped more readily between two charged spheres if light was shining on them. Further studies were done to learn about the effect observed by Hertz, however it wasn't until 1905 that a theory was proposed that explained the effect fully. The theory was proposed by Einstein and it made the claim that electromagnetic radiation had to be thought of as a series of particles, called photons, which collide with the electrons on the surface and emit them. This theory ran contrary to the belief that electromagnetic radiation was a wave and thus it was not recognised as correct until 1916 when Robert Millikan performed a series of experiments using a vacuum photo-tube to confirm the theory. Maxwell's wave theory of electromagnetic radiation's failure was due to it not able to explain the photoelectric effect and black body radiation, which was later explained by plank's quantum theory.
- Skoog, Douglas A., Stanley R. Crouch, and F. James. Holler. Principles of Instrumental Analysis. Belmont, CA: Thomson Brooks/cole, 2007. ISBN 0-495-01201-7
- Serway, Raymond A. (1990). Physics for Scientists & Engineers. Saunders. pp. p. 1150. ISBN 0030302587.CS1 maint: extra text (link)
- The American journal of science. (1880). New Haven: J.D. & E.S. Dana. Page 234
- Wolfram Scienceworld describes the terminology of the photoelectric effect and the previous usage of the term Hertz Effect.