Rhenium is a chemical element. It has the chemical symbol Re. It has the atomic number 75. It is a rare noble metal. It is silver white. In chemistry it is placed in a group of metal elements called the transition metals. The chemistry of rhenium is similar to manganese. Discovered in 1908, rhenium was the second-last stable element to be discovered ('stable' meaning not radioactive). It was named after the river Rhine in Europe.
Nickel-based superalloys of rhenium are used in the combustion chambers, turbine blades, and exhaust nozzles of jet engines. These alloys contain up to 6% rhenium, making jet engine construction the largest single use for the element. The second-most important use is as a catalyst: rhenium is an excellent catalyst for hydrogenation and isomerization.
Rhenium found as a by-product of molybdenum refinement.
Rhenium is used in some manganese alloys. Rhenium-molybdenum alloys are superconductors.
Rhenium was discovered by Walter Noddack, Ida Noddack, and Otto Berg in Germany. In 1925, they reported that they detected the element in a platinum ore and in the mineral columbite. They also found rhenium in gadolinite and molybdenite. In 1928, they were able to remove 1 g of the element from 660 kg of molybdenite.
Rhenium is a silvery-white metal. It has the third highest melting points of all elements. It is also the third densest element.
Rhenium has one stable isotope which is rhenium-185. Rhenium that is found in nature is made up of 37.4% rhenium-185 and 62.6% rhenium-187. Rhenium has 33 known radioisotopes. They range from rhenium-160 to rhenium-194. The longest-lived radioisotope of rhenium is rhenium-183 which have a half-life of 70 days.
Rhenium is one of the rarest elements in Earth's crust. It the 77th most abundant element in the Earth's crust. Rhenium may not be found free in nature. It is found in small amounts in the mineral molybdenite.
Commercial rhenium is gotten from molybdenum roaster-flue gas. Some molybdenum ores contain 0.001% to 0.2% rhenium. Rhenium metal is made by reducing ammonium perrhenate with hydrogen at high temperatures.
Nickel-based superalloys of rhenium are used in the combustion chambers, turbine blades, and exhaust nozzles of jet engines. Rhenium is used in superalloys, such as CMSX-4 (2nd generation) and CMSX-10 (3rd generation). These superalloys are used in industrial gas turbine engines like the GE 7FA. Rhenium filaments are used in mass spectrometers, ion gauges and photoflash lamps in photography. Rhenium-platinum alloys are used as a catalyst for catalytic reforming. Rhenium-188 and Rhenium-186 are used to treat of liver cancer.
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- ↑ "How to Change Nuclear Decay Rates". math.ucr.edu. Retrieved 2020-09-26.
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- ↑ Earle, G.D.; Medikonduri, R.; Rajagopal, N.; Narayanan, V.; Roddy, P.A. (2005). "Tungsten-rhenium filament lifetime variability in low pressure oxygen environments". IEEE Transactions on Plasma Science. 33 (5): 1736–1737. Bibcode:2005ITPS...33.1736E. doi:10.1109/TPS.2005.856413. ISSN 0093-3813. S2CID 26162679.
- ↑ Ede, Andrew. (2006). The chemical element : a historical perspective. Westport, Conn.: Greenwood Press. ISBN 0-313-33304-1. OCLC 64390389.
- ↑ Ryashentseva, Margarita A (1998-02-28). "Rhenium-containing catalysts in reactions of organic compounds". Russian Chemical Reviews. 67 (2): 157–177. Bibcode:1998RuCRv..67..157R. doi:10.1070/RC1998v067n02ABEH000390. ISSN 0036-021X. S2CID 250866233.
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