Selenium trioxide

chemical compound used in the manufacture of solar-energy devices

Selenium trioxide, also known as selenium(VI) oxide and selenic oxide, is a chemical compound. Its chemical formula is SeO3. It contains selenium in its +6 oxidation state. It also contains oxide ions.

Selenium trioxide structure

Properties

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Selenium trioxide is a white solid. It evaporates easily. It dissolves easily in water. It is not stable and breaks down to make selenium dioxide and oxygen when it is heated. It is a powerful oxidizing agent like all selenates. It dissolves in water to make selenic acid.

Preparation

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It can be made by reacting potassium selenate with sulfur dioxide. It can also be made by dehydrating (removing the water from) selenic acid with a strong dessicant, like phosphorus(V) oxide.

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