Wikipedia

Aluminium chloride

chemical compound

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Aluminium chloride
Names
IUPAC name
aluminium chloride
Other names
aluminium(III) chloride
aluminum trichloride
Identifiers
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| Gmelin Reference | 1876 |- |

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  • Cl[Al](Cl)Cl
  • dimer: Cl[Al-]1(Cl)[Cl+][Al-]([Cl+]1)(Cl)Cl

|- ! colspan=2 style="background: #f8eaba; text-align: center;" |Properties

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| AlCl3

|- | Molar mass

| 133.341 g/mol (anhydrous)
241.432 g/mol (hexahydrate)[1]

|- | Appearance | white or pale yellow solid,
hygroscopic |-

| Density | 2.48 g/cm3 (anhydrous)
2.398 g/cm3 (hexahydrate)[1] |- | Melting point | 192.6 °C (378.7 °F; 465.8 K)
(anhydrous)[1]
100 °C (212 °F; 373 K)
(hexahydrate, dec.)[1]

|- | Boiling point | 180 °C (356 °F; 453 K) (sublimes)[1]

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| 439 g/l (0 °C)
449 g/l (10 °C)
458 g/l (20 °C)
466 g/l (30 °C)
473 g/l (40 °C)
481 g/l (60 °C)
486 g/l (80 °C)
490 g/l (100 °C) |-

| Solubility | soluble in hydrogen chloride, ethanol, chloroform, carbon tetrachloride
slightly soluble in benzene |-




| Vapor pressure | 133.3 Pa (99 °C)
13.3 kPa (151 °C)[2] |-








| Viscosity | 0.35 cP (197 °C)
0.26 cP (237 °C)[2] |- ! colspan=2 style="background: #f8eaba; text-align: center;" |Structure

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| Monoclinic, mS16 |- |

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| C12/m1, No. 12[3] |-

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a = 0.591 nm

, b = 0.591 nm

, c = 1.752 nm[3]



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| 0.52996 nm3 |- |

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| 6 |- |

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| Octahedral (solid)
Tetrahedral (liquid) |- |

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| Trigonal planar
(monomeric vapour) |-

! align="center" cellspacing="3" style="border: 1px solid #C0C090; background-color: #F8EABA; margin-bottom: 3px;" colspan="2" | Thermochemistry |- | Std enthalpy of
formation ΔfHo298 | −704.2 kJ/mol[4] |-

| Standard molar
entropy So298 | 109.3 J/mol·K[4] |- | Specific heat capacity, C | 91.1 J/mol·K[4] |- ! colspan=2 style="background: #f8eaba; text-align: center;" |Pharmacology

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| D10AX01 (WHO) |- ! align="center" cellspacing="3" style="border: 1px solid #C0C090; background-color: #F8EABA; margin-bottom: 3px;" colspan="2" | Hazards

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| NFPA 704 |

0
3
2
 

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| U.S. Permissible
exposure limit (PEL) | none |- ! align="center" cellspacing="3" style="border: 1px solid #C0C090; background-color: #F8EABA; margin-bottom: 3px;" colspan="2" | Related compounds |- | Other anions | Aluminium fluoride
Aluminium bromide
Aluminium iodide |- | Other cations | Boron trichloride
Gallium trichloride
Indium(III) chloride
Magnesium chloride |-


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|} Aluminium chloride (AlCl3), is a chemical compound. It is a white or yellow crystalline solid. It melts at a low temperature. It is made by reacting aluminium oxide with hydrochloric acid. The anhydrous (without water) form may be made by reacting aluminium and chlorine. It is used in the making of chemicals. It is also used in deodorants. It can cause slight irritation.

Related pages change

Sources change

  1. ↑ 1.0 1.1 1.2 1.3 1.4 Haynes, William M., ed. (2011). CRC Handbook of Chemistry and Physics (92nd ed.). Boca Raton, FL: CRC Press. p. 4.45. ISBN 1439855110.
  2. ↑ 2.0 2.1 Aluminum chloride Archived 2014-05-05 at the Wayback Machine. Chemister.ru (2007-03-19). Retrieved on 2017-03-17.
  3. ↑ 3.0 3.1 Ketelaar, J.Α.A. (1935). "Die Kristallstruktur der Aluminiumhalogenide II". Zeitschrift für Kristallographie – Crystalline Materials. 90 (1–6): 237–255. doi:10.1524/zkri.1935.90.1.237. S2CID 100796636.
  4. ↑ 4.0 4.1 4.2 Haynes, William M., ed. (2011). CRC Handbook of Chemistry and Physics (92nd ed.). Boca Raton, FL: CRC Press. p. 5.5. ISBN 1439855110.


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