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Carbon monoxide, with the chemical formula CO, is a colorless, odorless, and tasteless gas. It consists of one carbon atom covalently bonded to one oxygen atom. It is made when carbon compounds burn and there is not enough oxygen. It is a good fuel and burns in air with a blue flame, making carbon dioxide. It is very toxic, but it is useful for modern technology as well.

Carbon monoxide
Ball-and-stick model of carbon monoxide
Spacefill model of carbon monoxide
Names
Preferred IUPAC name
Carbon monoxide
Other names
Carbon monooxide
Carbonous oxide
Carbon(II) oxide
Carbonyl
Flue gas
Monoxide
Identifiers
3D model (JSmol)
Beilstein Reference 3587264
ChEBI
ChemSpider
ECHA InfoCard 100.010.118
EC Number 211-128-3
Gmelin Reference 421
KEGG
MeSH {{{value}}}
PubChem {{{value}}}
RTECS number FG3500000
UNII
UN number 1016
SMILES {{{value}}}
Properties
CO
Molar mass 28.010 g/mol
Appearance colorless gas
Odor odorless
Density 789 kg/m3, liquid
1.250 kg/m3 at 0 °C, 1 atm
1.145 kg/m3 at 25 °C, 1 atm
Melting point −205.02 °C (−337.04 °F; 68.13 K)
Boiling point −191.5 °C (−312.7 °F; 81.6 K)
27.6 mg/L (25 °C)
Solubility soluble in chloroform, acetic acid, ethyl acetate, ethanol, ammonium hydroxide, benzene
kH 1.04 atm·m3/mol
−9.8·10−6 cm3/mol
1.0003364
0.122 D
Thermochemistry
Std enthalpy of
formation
ΔfHo298
−110.5 kJ/mol
Std enthalpy of
combustion
ΔcHo298
−283.4 kJ/mol
Standard molar
entropy
So298
197.7 J/(mol·K)
Specific heat capacity, C 29.1 J/(K·mol)
Hazards
EU classification Flammable F+ Very Toxic T+
NFPA 704

NFPA 704.svg

4
3
0
 
R-phrases R61 R12 R26 R48/23
S-phrases S53 S45
Explosive limits 12.5–74.2%
U.S. Permissible
exposure limit (PEL)
TWA 50 ppm (55 mg/m3)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

The most important use for carbon monoxide in industry is making iron from iron ore. The carbon monoxide takes the oxygen from the iron ore when heated in a large oven called a blast furnace. Liquid metal iron is left behind. The carbon monoxide turns into carbon dioxide.

Carbon monoxide can accidentally form when there is too little air to burn all the fuel into carbon dioxide. Such a situation may happen if the oven shutters are closed too early or if a mobile cooker is used in a small tent with no ventilation (Ventilation is fresh air coming in and smoke going out). Many people have died from carbon monoxide poisoning. Carbon monoxide poisoning can cause feelings of paranoia and hallucinations, and has been determined to be a major cause of "haunted" houses. Small amounts of it are found in coal gas, a fuel produced by heating coal without any air.

ProductionEdit

Despite that it is a poison, carbon monoxide is very useful in chemical industry so lots of ways of making it have been discovered.[2] Normally we burn coke at high temperature with not enough oxygen. Blast furnaces work this way. The chemical equation for this is:

2C + O2 → 2CO

It can be also made by blowing hot steam through red-hot crushed coke

C + H2O → CO + H2

Carbon monoxide can be used as heating fuel because it burns easily into carbon dioxide. It can also be used as so-called "synthesis gas" for making man-made gasoline in the Fischer-Tropsch process.

During the World War II when petrol was rare and reserved for the military, many cars were converted to use wood gas. It is carbon monoxide made by burning wood chips in insufficient amount of air. The wood gas was made in a special oven called generator, which was carried on the car. The resulting carbon monoxide was then used as fuel for the car itself. Even today there are cars which use wood gas as fuel.

ReferencesEdit

  1. GOV, NOAA Office of Response and Restoration, US. "CARBON MONOXIDE - CAMEO Chemicals - NOAA". cameochemicals.noaa.gov.
  2. Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. ISBN 0-12-352651-5.

Other websitesEdit