chemical element with symbol Li and atomic number 3

Lithium (from Greek lithos 'stone') is a soft, silver-white metal with symbol Li. It is the third chemical element in the periodic table. This means that it has 3 protons in its nucleus and 3 electrons around it. Its atomic number is 3. Its mass number is 6.94. It has two common isotopes, 6Li and 7Li. 7Li is more common; 92.5% of lithium is 7Li. Lithium is a soft silvery metal that is very reactive. It is used in lithium batteries and certain medicines. Lithium has 1 valence electron like all the alkali earth metals.

Lithium, 00Li
Lithium floating in oil
Pronunciation/ˈlɪθiəm/ (LITH-ee-əm)
Standard atomic weight Ar°(Li)
Lithium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson


Groupgroup 1: hydrogen and alkali metals
Periodperiod 2
Block  s-block
Electron configuration[He] 2s1
Electrons per shell2, 1
Physical properties
Phase at STPsolid
Melting point453.65 K ​(180.50 °C, ​356.90 °F)
Boiling point1603 K ​(1330 °C, ​2426 °F)
Density (near r.t.)0.534 g/cm3
when liquid (at m.p.)0.512 g/cm3
Critical point3220 K, 67 MPa (extrapolated)
Heat of fusion3.00 kJ/mol
Heat of vaporization136 kJ/mol
Molar heat capacity24.860 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 797 885 995 1144 1337 1610
Atomic properties
Oxidation states0[2], +1 (a strongly basic oxide)
ElectronegativityPauling scale: 0.98
Ionization energies
  • 1st: 520.2 kJ/mol
  • 2nd: 7298.1 kJ/mol
  • 3rd: 11815.0 kJ/mol
Atomic radiusempirical: 152 pm
Covalent radius128±7 pm
Van der Waals radius182 pm
Color lines in a spectral range
Spectral lines of lithium
Other properties
Natural occurrenceprimordial
Crystal structurebody-centered cubic (bcc)
Body-centered cubic crystal structure for lithium
Speed of sound thin rod6000 m/s (at 20 °C)
Thermal expansion46 µm/(m⋅K) (at 25 °C)
Thermal conductivity84.8 W/(m⋅K)
Electrical resistivity92.8 nΩ⋅m (at 20 °C)
Magnetic orderingparamagnetic
Molar magnetic susceptibility+14.2·10−6 cm3/mol (298 K)[3]
Young's modulus4.9 GPa
Shear modulus4.2 GPa
Bulk modulus11 GPa
Mohs hardness0.6
Brinell hardness5 MPa
CAS Number7439-93-2
DiscoveryJohan August Arfwedson (1817)
First isolationWilliam Thomas Brande (1821)
Isotopes of lithium
Main isotopes[4] Decay
abun­dance half-life (t1/2) mode pro­duct
6Li 4.85% stable
7Li 95.15% stable
 Category: Lithium
| references

Properties change

Physical properties change

Lithium is one of the alkali metals. Lithium is a silvery solid metal (when freshly cut). It is very soft. Thus it can be cut easily with a knife. It melts at a low temperature. It is very light, similar to wood. It is the least dense metal and the least dense element in a solid or liquid state. It can hold more heat than any other solid element. It conducts heat and electricity easily.

Chemical properties change

It will react with water, giving off hydrogen to form a basic solution (lithium hydroxide). Because of this, lithium must be stored in petroleum jelly. Sodium and potassium can be stored in oil but lithium cannot because it is so light. It will just float on the oil and not be protected by it.

Lithium also reacts with halogens. It can react with nitrogen gas to make lithium nitride. It reacts with air to make a black tarnish and then a white powder of lithium hydroxide and lithium carbonate.

Chemical compounds change

Flame test for lithium

Lithium forms chemical compounds with only one oxidation state: +1. Most of them are white and unreactive. They make a bright red color when heated in a flame. They are a little toxic. Most of them dissolve in water. Lithium carbonate is less soluble in water than the other alkali metal carbonates like sodium carbonate.

Occurrence change

It does not occur as an element in nature. It only is in the form of lithium compounds. The ocean has a large amount of lithium in it. Certain granites have large amounts of lithium. Most living things have lithium in them. There are some places where much lithium is in the salt. Some silicates have lithium in them.

The largest current find of lithium on Earth may be at the McDermitt Caldera near the Oregon-Nevada border. That's the Greater Yellowstone Ecosystem on this wiki.[5]

History change

Lithium (Greek lithos, meaning "stone") was discovered by Johann Arfvedson in 1817. In 1818, Christian Gmelin observed that lithium salts give a bright red color in flame. W.T. Brande and Sir Humphrey Davy later used electrolysis on lithium oxide to isolate the element. Lithium was first used in greases. Then nuclear weapons became a big use of lithium. Lithium was also used to make glass melt easier and make aluminium oxide melt easier in making aluminium. Now lithium is used mainly in batteries.

It was apparently given the name "lithium" because it was discovered from a mineral, while other common alkali metals were first discovered in plant tissue.

Preparation change

It is made by getting lithium chloride from pools and springs. The lithium chloride is melted and electrolyzed. This makes liquid lithium and chlorine.

Uses change

As an element change

Its main use is in batteries. Lithium is used as an anode in the lithium battery. It has more power than batteries with zinc, like alkaline cells. Lithium ion batteries also have lithium in them, though not as an element. It is also used in heat transfer alloys. Lithium is used to make organolithium compounds. They are used for very strong bases.

It is used to make special glasses and ceramics, including the Mount Palomar telescope's 200 inch mirror. Lithium is the lightest known metal and can be alloyed with aluminium, copper, manganese, and cadmium to make strong, lightweight metals for aircraft.

In chemical compounds change

Lithium compounds are used in some drugs known as mood stabilizers. Lithium niobate is used in radio transmitters in cell phones. Some lithium compounds are also used in ceramics. Lithium chloride can absorb water from other things. Some lithium compounds are used to make soap and grease. Lithium carbonate is used as a drug to treat manic depression disorder. Lithium carbonate is used for the treatment of bipolar disease and other mental illness conditions.

Organic chemistry change

Organolithium compounds are used to make polymers and fine chemicals.[6] Many lithium compounds are used as reagents to make organic compounds. Some lithium compounds like lithium aluminium hydride, lithium triethylborohydride, n-butyllithium and tert-butyllithium are commonly used as very strong bases called superbases.

Other uses change

Lithium battery Model

Lithium compounds are used as pyrotechnic colorants and oxidizers in red fireworks and flares.[6][7] Lithium chloride and lithium bromide are used as desiccants for gas streams.[6] Lithium hydroxide and lithium peroxide are used to remove carbon dioxide and purify the air in spacecrafts and submarines.[8] Lithium hydroxide, lithium peroxide and lithium perchlorate are used in oxygen candles that supply submarines with oxygen.[6]

Lithium aluminum hydride can also be used as a solid fuel by itself. Lithium hydride that contains lithium-6 is used in thermonuclear weapons.[9]

Safety change

Lithium reacts with water, making irritating smoke and heat. It is not as dangerous as the other alkali metals. Lithium hydroxide is very corrosive. Lithium fires must not be put out with water or an ordinary fire extinguisher. A lithium fire can only be put out with a class D fire extinguisher.

Isotopes change

There are 5 isotopes of Lithium having respectively 2, 3, 4, 5 and 6 neutrons in the nucleus. The most common isotope in nature is 3Li7 which makes up 92.58% of the total. The second isotope which is widely available is 3Li6 which makes up 7.42% of the total. The other 3 isotopes exist in very small quantities. The atomic mass of Lithium is 6.939.

Related pages change

References change

  1. "Standard Atomic Weights: Lithium". CIAAW. 2009.
  2. Li(0) atoms have been observed in various small lithium-chloride clusters; see Milovanović, Milan; Veličković, Suzana; Veljkovićb, Filip; Jerosimić, Stanka (October 30, 2017). "Structure and stability of small lithium-chloride LinClm(0,1+) (n ≥ m, n = 1–6, m = 1–3) clusters". Physical Chemistry Chemical Physics. 19 (45): 30481–30497. doi:10.1039/C7CP04181K. PMID 29114648.
  3. Weast, Robert (1984). CRC, Handbook of Chemistry and Physics. Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN 0-8493-0464-4.
  4. Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  5. Peter Zeihan on [1]
  6. 6.0 6.1 6.2 6.3 CRC handbook of chemistry and physics, 2000-2001. Lide, David R., 1928- (81st ed.). Boca Raton: CRC Press. 2000. ISBN 0-8493-0481-4. OCLC 44440496. Retrieved 2020-09-20.{{cite book}}: CS1 maint: others (link)
  7. Wiberg, Egon. (2001). Inorganic chemistry. Wiberg, Nils., Holleman, A. F. (Arnold Frederick), 1859-1953. (1st English ed.). San Diego: Academic Press. ISBN 0-12-352651-5. OCLC 48056955. Retrieved 2020-09-20.
  8. Air quality in airplane cabins and similar enclosed spaces. Hocking, M. B. (Martin Blake), 1938-. Berlin: Springer. 2005. ISBN 978-3-540-31491-2. OCLC 262680730. Retrieved 2020-09-20.{{cite book}}: CS1 maint: others (link)
  9. Emsley, John. (2011). Nature's building blocks : an A-Z guide to the elements. Oxford University Press. ISBN 978-0-19-960563-7. OCLC 758646995. Retrieved 2020-09-20.